Carbonate minerals are salts or esters of carbonic acid that contain the ion, CO32-. They make up over 15% of all sedimentary rocks on Earth and are vital compounds found throughout the geological and biological realms. Its rocks like limestone, dolostone, and marble are formed from the accumulation and compaction of shallow marine organisms, coral, algae, and plant fragments that have in their shells or skeletal structure.
Formation of Minerals:
Carbonate minerals form through various geological and biological processes. Many are the results of marine organisms that rely on calcium to build their hard body parts. For example, coral reefs are built from the calcium exoskeletons of billions of tiny coral polyps. When coral polyps and other marine life die, their remains settle on the ocean floor and over immense time periods compact into limestone and dolostone under heat and pressure within the Earth. Carbon dioxide and calcium-rich groundwater can also naturally combine abiotically to precipitate out rocks via chemical and hydrothermal reactions within the crust over millions of years.
Common Minerals:
Calcite: By far the most ubiquitous carbonate mineral, calcite forms the shells of foraminifera (microscopic plankton), coral exoskeletons, and limestone rocks. Calcite crystals can range in color from colorless to white, yellow, green, or black depending on impurities. Calcite makes up approximately 4% of the Earth's crust.
Aragonite: With the same chemical formula as calcite (CaCO3) but different crystalline structure, aragonite commonly forms the inner layer of mollusk shells like nautilus and oysters. Aragonite precipitates out of hot springs and geysers and also exists as deep ocean inorganic deposits.
Dolomite: Possessing the formula CaMg(CO3)2, dolomite rocks give the Appalachian Mountains their name. They derive from the magnesium substitution that replaces calcite's calcium. Hydrous magnesium alteration of calcite produces the pale pink/brown rock dolomite prized in construction.
Siderite: With formula FeCO3, siderite lends its name to the term "sideritic" used to describe iron-rich sedimentary rocks and soil. Dark grey to brownish-black siderite forms as a diagenetic product in swamps, bogs, and other waterlogged reducing environments.
Magnesite: Composed of magnesium Carbonate (MgCO3), magnesite is a common polymorph found in serpentinite rocks undergoing carbonation reactions. Massive seafloor and ophiolite magnesite deposits also exist, tapped as a raw material in refractory and steelmaking industries.
Uses of Minerals
Given the abundance of carbonates worldwide, they hold many industrial roles serving humanity. Limestone quarrying yields crushed stone for road base, concrete aggregate, cement manufacture, and agricultural applications like soil amendment. Marble slabs cut from metamorphosed limestone decorate buildings as durable flooring and interior/exterior cladding. In chemical manufacturing, act as pH buffers and react with acids to sequester pollutants in water/soil remediation. The paper industry relies on it as pigments and fillers to improve brightness and surface properties.
Impacts and Environmental Concerns
While rocks foster biologically rich ecosystems, their dissolution impacts aquifer and cave systems through subsurface corrosion. Agricultural practices like the spreading of lime for its alkaline properties can raise runoff pH entering streams, affecting sensitive biota. Opencast mining and quarrying of carbonate deposits causes landscape damage and loss of geologic strata that offer insights into Earth history. Global sediment production also acts as an important long-term carbon sink, counteracting greenhouse gas emissions on million-year timescales. Overall, understanding this major rock-forming mineral group aids the sustainable use and stewardship of natural resources.
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